In 1589, the four French Secretaries of State became specialized, with one of the secretaries responsible for foreign affairs. Since then, France has usually had a Foreign Minister, with a few brief exceptions.
June 13 - September 20, 1792: not listed (there were two, I think, but they aren't listed on the official French foreign ministry site, or any other common reference sources)
... Dumont d'Urville, (1790-1842), explorer of the Pacific and Antarctica
E
Eric the Red, (c.950-1003), explored and colonized Greenland
Leif Ericsson, ...