It is also possible to use eutectic salts.
In some cases, refrigeration by material at ambient temperature is acceptable, for example the fan cooling of computer equipment.
Where temperatures below that of any available natural cooling agent are required, refrigerators are used to produce the required cooling effect by taking in heat at low temperatures and rejecting it at temperatures somewhat above that of the natural cooling agent, which for obvious reasons is generally water or air. The function of a refrigerating machine, therefore, is to take in heat at a low temperature and reject it at a higher one, using external energy to drive the process. A refrigerator is effectively a heat pump, a heat engine running in reverse.
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Thermodynamics of refrigerators
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