The word "unobtainium" is an informal one, apparently developed within science fiction fandom, and probably in ironic reaction to invented element names in, for example, Star Trek; maybe also by analogy with the naming system for the heaviest actual elements.
An alternative source for "unobtainium" exists within the aerospace industry, which has frequently encountered design problems beyond the capabilities of the available materials. Engineers working for Lockheed Corporation at the Skunk works refer to the SR-71 Blackbird as being being made of "unobtainium" because of the radical decision to use an untried new material, titanium in the construction of this remarkable aeroplane. At the time, "Unobtainium" was required because no known material could withstand the extreme temperatures and stresses of exposure to a Mach 3 airstream.
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