General | |
---|---|
Name | Hydrogen cyanide |
Chemical formula | HCN |
Appearance | Colourless liquid |
Physical | |
Formula weight | 27.0 amu |
Melting point | 260 K (-13 °C) |
Boiling point | 299 K (26 °C) |
Density | 0.7 ×103 kg/m3 |
Solubility | very soluble |
Thermochemistry | |
ΔfH0gas | 135.14 kJ/mol |
ΔfH0liquid | 109 kJ/mol |
ΔfH0solid | 100 kJ/mol |
S0gas, 1 bar | 201.82 J/mol·K |
S0liquid, 1 bar | 113.01 J/mol·K |
S0solid | ? J/mol·K |
Safety | |
Ingestion | Extremely toxic. Early symptoms include nausea, vomiting and abdominal pain. |
Inhalation | Extremely dangerous. Early symptoms include slow breathing rate, irritation. |
Skin | Poisoning is thought to be possible through the skin. |
Eyes | Dilated pupils are a symptom of poisoning. |
More info | Hazardous Chemical Database (http://ull.chemistry.uakron.edu/erd/chemicals/7/6581) |
SI units were used where possible. Unless otherwise stated, standard conditions were used. |
The carbon atom (C) is triple bonded to the nitrogen atom (N). The compound melts at -14°C and boils at 26°C. A simple way to produce the gas is by reduction of potassium ferrocyanide solution.
Hydrogen cyanide is weakly acidic and partly converts to the cyanide ion CN– in solution. Such a solution is called prussic acid or hydrocyanic acid.
An HCN concentration of 300 parts per million of air will kill a human in a few minutes. The toxicity is caused by the cyanide ion. The mechanism of this toxicity, and the uses of the poison, are described on the cyanide page.
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