Pi mesons have zero spin and are composed of first generation quarks. An up and an anti-down quark compose a pi-plus, while a down and an anti-up quark compose the pi-minus, its antiparticle. Combinations of up and anti-up, or down and anti-down, would both be neutral, but because they have the same quantum numbers are only found in superpositions. The lowest energy superposition is the pi-zero, and it is its own antiparticle.
The pi-plus (π+) and pi-minus (π-) may combine to form an exotic atom called pionium, if they are created close to each other with a small relative momentum.
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