Redirected from Photoconductor
LDR's are made of a high resistance semiconductor. If light falling on the device is of high enough frequency, photons absorbed by the semiconductor give bound electrons enough energy to jump into the conduction band. The resulting free electron (and its hole partner) conduct electricity, thereby lowering resistance.
In intrinsic devices, the only available electrons are in the valence band, and hence the photon must have enough energy to excite the electron across the entire bandgap. Extrinsic devices have impurities added, which have a ground state energy closer to the conduction band - since the electrons don't have so far to jump, lower energy photons (i.e. longer wavelengths and lower frequencies) will suffice to trigger the device.
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