Memory effect

Memory effect, also known as lazy battery effect, is an effect seen in some rechargeable batteries that causes them to apparently hold less charge. The term has become almost universal in describing any such effect, although in fact it describes one very specific one.

Memory effect occurs when a sintered-plate nickel cadmium (NiCd) battery is repeatedly discharged to a particular level above a full discharge, that is, only "partically used", and then re-charged to an equally precise "full" level. This "real" memory effect is extremely rare and is found only on very expensive, rare and older unattended electronics like communications satellites. Repeated tests to attempt to duplicate it in the lab have proven difficult.

Voltage depression is a much more common effect that many ascribe to memory effect. In this case the peak voltage of the battery drops more quickly than normal as it is used, even though the total power remains almost the same. In modern electronics equipment that monitor the voltage to indicate battery charge, the battery is seen as being drained very quickly and therefore about to run out of power. To the user it appears that the battery is not holding a full charge, which seems similar to memory effect. This problem a common complaint on high-load devices like digital cameras.

Voltage depression is caused by the repeated over-charging of the battery, which leads to the formation of small crystals of electrolyte forming on the plates. These can clog up the plates, increasing resistance, and thereby dropping the voltage of some of individual cells of the battery. This results in a seeming rapid discharge as those individual cells discharge quickly and the voltage of the battery as a whole suddenly drops. This effect is very common as consumer trickle chargers[?] overcharge every time.

Urban rumors[?] about the memory effect, universally referring to voltage depression, have led to all sorts of quasi-religeous behaviour in order to "fix" dead batteries. The most common suggestion is to completely drain the batteries in some other device in order to dissolve the crystals. While this works in theory, it more often leads to damage to the other cells in the battery, correcting the problem for a short time but leading to a considerably shorter overall lifetime.

Voltage depression does not occur in nickel hydride[?] (NiMH) batteries because the electrolyte does not crystalize, which is why these types of batteries have become increasingly in demand for most electronics that are repeatedly charged, like laptop computers[?] and cell phones. Most advertising for NiMH batteries includes the claim that they are immune to the memory effect, although cell degradation and voltage depresssion in general are just as common as with NiCd.

External links:

NiCd Batteries do NOT have "memory" (http://www.repairfaq.org/ELE/F_NiCd_Memory)