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Beer-Lambert law

The Beer-Lambert law, also known as Beer's law or the Beer-Lambert-Bouguer law is an empirical equation in optics relating the absorption of light to the properties of the material the light is travelling through. It was independently discovered (in various forms) by Pierre Bouguer[?] in 1729, Johann Heinrich Lambert in 1760 and August Beer[?] in 1852.

                              
              | . . . . . . |
     I0  ==>  |. . c,α . . .|   ==>  I1
              | . . . . . . |
              
              <- - - l - - ->

The most common statement of the law is:

<math> {I_{1}\over I_{0}} = e^{-\alpha l c}\; , </math>

where I0 is the intensity of the incident light, I1 is the intensity after passing through the material, l is the distance that the light travels through the material (the path length), c is the concentration of absorbing species in the material and α is the absorption coefficient of the absorber.

In essence, the law states that there is an exponential dependence between the transmission of light through a substance and the concentration of the substance, and also between the transmission and the length of material that the light travels through. Thus if l and α are known, the concentration of a substance can be deduced from the amount of light transmitted by it.

The units of c and α depend on the way that the concentration of the absorber is being expressed. If the material is a liquid, it is usual to express the absorber concentration c as a mole fraction i.e. a dimensionless fraction. The units of α are thus reciprocal length (e.g. cm-1). In the case of a gas, c may be expressed as a density (units of reciprocal length cubed, e.g. cm-3), in which case α is an absorption cross-section and has units of length squared (e.g. cm2).

The value of the absoption coefficient α varies between different absorping materials and also with wavelength for a particular material. It is usually determined by experiment.

The law tends to break down at very high concentrations, especially if the material is highly scattering[?]. If the light is especially intense, nonlinear optical processes can also cause variances.

The law's link between concentration and light absorption is the basis behind the use of spectroscopy to identify substances.

See also: absorption.



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